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Definition of Toe jam
1. Noun. (uncountable slang) Sticky matter accumulated between digits of a foot. ¹
2. Noun. A stubbed toe. ¹
3. Noun. A rock-climbing maneuver entailing exerting force with two opposite surfaces of the toe of a shod foot, against two different rock surfaces, for the purpose of preventing motion of that foot in a direction parallel to both of those rock surfaces. ¹
¹ Source: wiktionary.com